1. Annie Leibovitz, Angelina Jolie, 2005
2. SS: 125 Reason: It is cloudy so you need to have a shutter speed that lets in a good amount of light without overexposing because there is direct light on her face. Her face is also just slightly blurred so the shutter speed couldn't be fast enough to perfectly capture her movement
3. F5.6 Reason: The Gargoyles and she are the only subjects in the foreground and everything else in the background is out of focus
4. ISO200 Reason: There is no grain or noise in this picture